O próprio manual tem um exemplo disto... // To send HTML mail, the Content-type header must be set
$headers = 'MIME-Version: 1.0' . "\r\n";
$headers .= 'Content-type: text/html; charset=iso-8859-1' . "\r\n";
// Additional headers
$headers .= 'To: Mary <mary@example.com>, Kelly <kelly@example.com>' . "\r\n";
$headers .= 'From: Birthday Reminder <birthday@example.com>' . "\r\n";
$headers .= 'Cc: birthdayarchive@example.com' . "\r\n";
$headers .= 'Bcc: birthdaycheck@example.com' . "\r\n";
// Mail it
mail($to, $subject, $message, $headers); http://br2.php.net/manual/pt_BR/function.mail.php